Dynamic nuclear polarization system output volume reduction using inert fluids

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Cross-polarization for dissolution dynamic nuclear polarization.

Dynamic nuclear polarization (DNP) in combination with subsequent dissolution of the sample allows the detection of low-γ nuclei in the solution state with a signal gain of up to tens of thousand times compared to experiments starting from Boltzmann conditions. The long polarization build-up times of typically more than one hour are a drawback of this technique. The combination of dissolution D...

متن کامل

Chemically Induced Dynamic Nuclear Polarization

N M R emission and e n h a n c e d absorpt i on o f p roduc t s o f radical react ions ( C I D N P ) is e x p l a i n e d b y nuc lear spin d e p e n d e n t ad iabat i c transit ions be tween singlet a n d tr iplet states o f transient radical pairs. I n m a g n e t i c fields larger than a b o u t 1 k G o n l y S — To-transit ions c ont r ibute t o nuc lear polar izat ion. F r o m a k inet i ...

متن کامل

Portable X-band system for solution state dynamic nuclear polarization.

This paper concerns instrumental approaches to obtain large dynamic nuclear polarization (DNP) enhancements in a completely portable system. We show that at fields of 0.35 T under ambient conditions and at X-band frequencies, 1H enhancements of >100-fold can be achieved using nitroxide radical systems, which is near the theoretical maximum for 1H polarization using the Overhauser effect at this...

متن کامل

High frequency dynamic nuclear polarization.

During the three decades 1980-2010, magic angle spinning (MAS) NMR developed into the method of choice to examine many chemical, physical, and biological problems. In particular, a variety of dipolar recoupling methods to measure distances and torsion angles can now constrain molecular structures to high resolution. However, applications are often limited by the low sensitivity of the experimen...

متن کامل

Optimizing dissolution dynamic nuclear polarization.

This article is a short review of some of our recent developments in dissolution dynamic nuclear polarization (d-DNP). We present the basic principles of d-DNP, and motivate our choice to step away from conventional approaches. We then introduce a modified d-DNP recipe that can be summed up as follows. (i) Using broad line polarizing agents to efficiently polarize 1H spins. (ii) Increasing the ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Magnetic Resonance Imaging

سال: 2011

ISSN: 1053-1807

DOI: 10.1002/jmri.22498